5/16/2023 0 Comments Halo memes![]() His email is, and available privately on Signal (22). But also working in writing for where we're having the intersection of little hidden strands of deep lore, but also making a really cool story that is compelling for everyone.”Īnd that deep lore, it turns out, includes Craig.įollow Patrick on Twitter. “Simultaneously, we're working on writing an encyclopedia that comes out next year that covers 20 years of deep Halo lore. “Honestly, that's been one of the coolest things for me,” said Halo franchise and narrative writer Jeff Easterling. Halo is a military science-fiction series based on the video game series of the same name. To this day, there are communities specifically for sharing memes about the. “That's just a way in which we're trying to embrace some of our more public missteps, but also try and take it into a new phase.” Credit:arbychiefhalo4ever1996haloshitpostshalounfunnieschips.dubboplasmicalsrememberhaloslipspaceentertainment Thumbnail: halo.stellar Please go s. Halo is a cultural phenomenon, and it has been since the late 2000s when the meme-sharing site Halolz was founded. “There is stuff about Craig defined in the game, as well,” said Crocker, echoing what 343’s alluded to about Craig becoming more than meme. The campaign, however, will not arrive until early December 8.Ĭraig came up in my group conversation with Crocker and other members of the Halo Infinite development team after I asked people for their favorite piece of obscure Halo lore. This comes amid a swell of goodwill towards the part of Halo Infinite that players have had a chance to mess with so far, the multiplayer that surprise dropped earlier this week. ![]() In that sense, Craig has come to represent some of what 343 has done with the past year the game (and Craig) do look better. ![]()
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5/16/2023 0 Comments Malist lyrics![]() ![]() Runners-up Malist – In the Catacombs of TimeĪtmospheric, dark and sinister. This black metal band from Russia is one of the most promising new acts I’ve heard in a long time. Released January 25th via Northern Silence Productions. What can I say I am a sucker for old school death metal. Finnish Festerday are veterans of the scene and shows the old dogs got bark. Their blend of death metal with both punk and even hints of grind elements to it makes it stand out. Released January 4th via Season of Mist Underground Activists. With a new direction from their previous releases and lyrics that draws influences from Warhammer, Diablo, Doom the third album from Rendered Helpless became an instant hit to me. A change that was much needed for me to get into the band for real! Released January 25th, 2019 as an digital independent release. ![]() It was my most anticipated album of 2019 and while it didn’t quite live up to those it’s still a very solid death metal album. Seeing the loss the band had I am honestly surprised they are still going, and going hard too! Released January 18th via Century Media Records. Thanks for reading, hope you enjoy this new segment of The Metal Gamer and that it gives you some new great music! Did I miss any great album? What’s your top five of the month? Feel free to comment metal gamers! Who knows if they would of knocked one of those mentioned above if I had more time with them though? I also need to name some honorable mentions that I’ve had a few spins with but didn’t quite make it. Japan’s very own answer to Origin are back with their third full-length album! After a change in the line-up since their last critically acclaimed album Orphic Signs I was interested to hear what that would do to Desecravity’s sound. I mean not only is Shogo Tokita a great guitarist, he also did vocals in the band so it’s not an easy member to replace. Now the growling duty falls solely on Yujiro Suzuki (who plays guitar as well), while they’ve added Yuya Takeda (Deadly Spawn) on guitar to the band.Īfter a beautiful intro on the epic side in Aeon and Ashes the technical brutality is unleashed on Impure Confrontation, the single I’d heard many times before but still haven’t got tired of. The utter chaos is created with such a technical precision it’s almost silly. Bands like Defeated Sanity, Origin and Cryptopsy will be proud to know there are bands like Desecravity out there that keeps the legacy going for years to come. If you think Impure Confrontation left you breathless then wait for Ominous Harbinger and Bloodthirsty Brutes which are two of the heaviest tracks I’ve heard in a long time and an instant favorites of mine. Anathema never lets you breath either, track after track it hits you with fast, technical and skull splitting tunes for you to devour and after the ride is over you will need to sit back, relax and take in just what the hell just happened to your now blown mind. ![]() 5/16/2023 0 Comments Mailbutler scheduled email![]() ![]() Rubio serviced samples inside the Electrostatic Levitation Furnace, a research device that safely investigates the thermophysical properties of high temperature phenomena using a containerless, levitation technique. Rubio and Hoburg worked on a pair of different physics experiments on Tuesday, one exploring extreme temperatures and the other foams and emulsions. Observations may advance the design and safety of spacecraft and space habitats as well as improve a host of ground-based industries and products. Space physics is also a key research topic as scientists and engineers learn how Earth-created materials react to the microgravity environment under a variety of conditions. Additionally, Prokopyev, who is also commander of the orbiting lab, and Petelin participated in a hearing test to evaluate the condition of their ear drums. The trio took turns imaging the eyes of fellow crewmates Woody Hoburg of NASA, Sultan Alneyadi of UAE (United Arab Emirates), and Sergey Prokopyev of Roscosmos using standard medical imaging gear found in an optometrist’s office on Earth. He then scanned his veins using an ultrasound device and measured his blood pressure with inputs from doctors on the ground.īowen then swapped roles as Crew Medical Officer with flight engineers Frank Rubio of NASA and Dmitri Petelin of Roscosmos for eye checks during the afternoon. NASA Flight Engineer Stephen Bowen contributed to that research on Tuesday attaching electrodes to himself and marking his neck, leg, and heart veins for the Vascular Aging investigation. Researchers regularly evaluate the health of station crew members to gain insights into space-caused and Earth-bound heart conditions. Living long-term in weightlessness is suspected of increasing cardiovascular health risks such as aging-like symptoms in blood vessels observed in astronauts on previous missions. ![]() Space physics also rounded out the science schedule while the orbital residents also continued ongoing cargo and maintenance operations. Human research activities dominated the Expedition 69 crew’s schedule aboard the International Space Station on Tuesday with ultrasound scans, vision checks, and hearing exams. Also, there is a professional, and a corporate plan.Astronaut Sultan Alneyadi receives a haircut from astronaut Frank Rubio aboard the space station with a hair trimmer containing a suction device collecting loose hair. It offers a free plan, which allows you up to 20 actions per month. It reminds you when you’ve forgotten the attachment, which you mentioned in the text of the email ![]() It gives you the opportunity to undo the delivery of the email you’ve already sent It personalizes your incoming emails by assigning the senders’ representative images to them It gives you the choice between various beautiful signatures, which you can also alter according to your personality With it, you can easily attach the files of any size to your emails ![]() It helps you convert your emails directly into perfectly composed notes It lets you schedule your emails for any time in the future It can be easily installed on your computer and managed from your personal MailButler account Use it for business or private purposes – MailButler will become an indispensable, reliable servant once you start using it. With its various functions, it simplifies, optimizes and streamlines working with emails in your daily life. MailButler is your personal assistant for efficient and productive work with Apple Mail. ![]() 5/16/2023 0 Comments Jamf pro vs jamf now![]() There were some issues with the way you have to register your device into Intune." "It would be nice if Jamf added an onboarding tool integrated into Jamf Connect during the automated DEP enrollment workflow. They shouldn't be like add-ons." "We had some issues with its integration with other products, such as Intune. They can make some of the extension attributes the actual attributes. "The patch management needs improvement in Jamf Pro." "We would like to have some of the extension attributes configured so that those extension attributes can be part of the core structure. We also use this to send applications to devices." ![]() And when the device is not there, the policy goes away." "Jamf Pro allows us to manage all Apple devices from a single interface, making it easy to deploy and configure software, set policies, and inventory devices." "The solution has good integration with Google and has high performance for our Mac fleet of devices." "It offers professionals an endless amount of possibilities to keep users and the company happy." "The ease of use and access allows us to manage all of our devices collaboratively." "Jamf Pro has allowed us to make sure settings for our devices are easily installed so our end-users don't need to worry about a significant amount of steps for setup. If the device is on a particular premise, then the policy applies. With Jamf Now, employees can receive new, fully configured Apple devices to all your company specs without anyone ever physically touching the device."We can put certain devices into smart groups based off of device name, department, etc." "We like the pre-stage enrollments." "One of the key features that I liked the most and a lot of the customer value as well is the geofencing. Since Jamf Now doesn't subscribe to that unified endpoint management (UEM) philosophy, they've crafted a handful of separate yet interconnected apps to govern all phases of a company-provided iPhone or iPad's life. And since many businesses don't have the ability to hire dedicated IT personnel, Jamf Now makes it simple for almost any manager to oversee all those devices, even if they aren't tech-savvy themselves. Jamf Now streamlines remote device oversight, making it easier for even one person to handle and manage the iPhone, iPad, Mac and Apple TV devices, apps, and corporate resources for every employee company-wide. It has to be managed and managed effectively, which is where software like Jamf Now becomes unbelievably important for small to medium-sized companies. With all that intricacy and customization going into an integrated digital business network, device management can't be piecemealed. If you see inaccuracies in our content, please report the mistake via this form. If we have made an error or published misleading information, we will correct or clarify the article. Our editors thoroughly review and fact-check every article to ensure that our content meets the highest standards. Our goal is to deliver the most accurate information and the most knowledgeable advice possible in order to help you make smarter buying decisions on tech gear and a wide array of products and services. ZDNET's editorial team writes on behalf of you, our reader. Indeed, we follow strict guidelines that ensure our editorial content is never influenced by advertisers. Neither ZDNET nor the author are compensated for these independent reviews. This helps support our work, but does not affect what we cover or how, and it does not affect the price you pay. When you click through from our site to a retailer and buy a product or service, we may earn affiliate commissions. ![]() And we pore over customer reviews to find out what matters to real people who already own and use the products and services we’re assessing. ![]() We gather data from the best available sources, including vendor and retailer listings as well as other relevant and independent reviews sites. ZDNET's recommendations are based on many hours of testing, research, and comparison shopping. ![]() 5/16/2023 0 Comments Anaconda navigator vscode missing![]() However, doing so gives you more control over what your workspace looks like, contains, and does.īeyond the setup, I’ve found VS Code easier to navigate, understand, and work with as the interface is beginner-friendly, welcoming, and easy to navigate. To set up VS Code, you’d have to spend some time customizing to your Python needs, which would require you to review and download various extensions like Python, Python Indent, Python Snippets, and others. Therefore, after installing P圜harm on your machine, it does not require much for you to start writing your code. However, P圜harm was explicitly made for Python, while Microsoft created VS Code for language polyglots. Setting up both P圜harm and VS Code is fairly easy. If managing your computer’s resources is a top priority, VS Code is a better option. Likely on account of the difference in size, P圜harm took about three to five minutes to load and open on my machine, while VS Code started up instantly. ![]() On the other hand, VS Code is exceptionally lightweight, requiring only about 76.2MB to download and consuming only about 40MB of memory on my computer. However, when I run P圜harm on my system, it consumes about 400MB of memory, which in my opinion, is significant. P圜harm memory consumptionĭownloading the community version of P圜harm requires about 372MB, which probably doesn’t seem like a lot. You want to choose a tool that will take up minimal space, use minimal RAM, and run smoothly on your computer system without causing it to lag. You can install as many plugins as you need or want, all for free. ![]() VS Code doesn’t come with any plugins pre-installed, so you’ll have to manually install the necessary plugins for your Python project. Features like version control, third-party integrations, and bug tracking come out of the box with VS Code regardless of the type of project or language you intend to write with it. On the other hand, VS Code is an open source project and is free for commercial and private use. However, both versions lack certain features, like support for remote development, a Python profiler, duplicate code detection, database support, and some web development tools. The P圜harm community and Edu editions are both free, open source projects. The professional edition for organizations costs $199 for the first year, $159 for the second year, and $119 for subsequent years. For one, the professional edition for individuals costs $89 for the first year, $71 for the second, and $53 for the third year onwards. In this article, we’ll compare P圜harm and VS Code using the following metrics: price, memory consumption, setup process, code management, extensions, and Git integration. However, it is vital to note that while P圜harm is an IDE, VS Code is a code editor that provides a similar experience to an IDE through extensions. ![]() P圜harm and VS Code are both excellent tools for writing Python code. I also faced this challenge, and while there are several IDEs and code editors available for Python, P圜harm and VS Code have remained favorites of Python developers over the years. However, beginners often have to ask themselves what integrated development environment (IDE) or editor to use. Python is beginner-friendly, has a relatively simple syntax, is supported by its community with lots of libraries and frameworks, and is very versatile. Therefore, it’s not a huge surprise that a lot of people begin programming with Python, myself included. Python is one of the most popular programming languages globally and has been said to be very easy to learn. Oyinkansola Awosan Follow I'm a fun techie and passionate technical writer interested in data science, machine learning, cloud engineering, and blockchain technologies. ![]() 5/16/2023 0 Comments Nba 2k19 cover ps4![]() ![]() ![]() However, there's one more sneaky detail you've probably not spotted. Wherther James is the main cover athlete for the standard edition isn't clear, but he will certainly be on this Anniversary edition, which appears to also offer access to the game 4 days early. Well, from the standee we can confirm that Lebron James will be a cover star for the game, which is coming out on September 7. ![]() However, it's difficult to look past the fact that both the standee and the logo tweeted by 2K Games is unmistakably the same, therefore pretty much rubber stamping the leak as genuine. However it may be necessary to resolve your crashing issue. Be warned though this will remove mostly all game files, data files, user settings, file saves and more. It appears as though the games cover athlete and release date has already been leaked via some in store merchandising props.Ī few outlets have spoken with 2K Games but to be honest they won't confirm anything until they're good and ready. Confirm to Re-install and Fix NBA 2K19 Select the NBA 2K19 file and choose to un-install. Original Story - 2K Games official kickstarted their campaign to promote their next NBA game last night as the game casually tweeted out a new teaser that simply said "#NBA 2K19" along with an image that was equally minimalist, that read: "They Will Know Your Name". Anyone who decides to play the game on PS4 or Xbox One can download NBA 2K19: The Prelude on August 31 if they want to get a head. We've got all the details you need on the link above, but for the time being, you can also check out the brand new trailer for the game, just below: Both versions will come to PS4, Xbox One, PC, and Switch. The next NBA 2K game will feature three-time NBA Champion, four-time NBA MVP and avid NBA 2K gamer LeBron James on the cover of the NBA 2K19 20th Anniversary Edition. If you’d like to print out an updated cover, please see below for links to all the different regional files.2K has now confirmed what we already knew. : NBA 2K19 20th Anniversary Edition - PS4 : Take 2 Interactive: Video Games Video Games PlayStation 4 Buy new: 6492 3. Interestingly, they’ve also released downloadable versions of the original cover, presumably for anyone who’d like to replace the Celtics cover when it’s in circulation, or perhaps the Legend Edition cover featuring Shaquille O’Neal, if you’re a big Kyrie Irving and Cavs fan. However, if you’ve got a physical copy of NBA 2K18 and you’d like to replace the cover in the meantime, 2K has released downloadable versions of the new artwork which you can print out and slide right into the case. Once this stock has been depleted, new copies of NBA 2K18 will feature the revised cover. NBA 2K19 - PlayStation 4 Visit the 2K Store Platform : PlayStation 4 Rated: Everyone 4,314 ratings -29 1105 Was: 15.60 Get Fast, Free Shipping with Amazon Prime FREE Returns Available at a lower price from other sellers that may not offer free Prime shipping. Although the title screen and digital covers for the game were already updated at launch, the initial run of copies featured the original cover with Irving wearing a Cleveland Cavaliers jersey. That NBA 2K18 cover was revealed last June, which means we’re likely just weeks away from finding out who will grace the cover of NBA 2K19. After Kyrie Irving was traded to the Boston Celtics, 2K announced that they would be issuing an updated cover for NBA 2K18. ![]() 5/16/2023 0 Comments Golden flake chips![]() ![]() Strategic Points Covered in Table of Content of Global Potato Chips Market:Ĭhapter 1: Introduction, market driving force product Objective of Study and Research Scope the Potato Chips marketĬhapter 2: Exclusive Summary - the basic information of the Potato Chips Market.Ĭhapter 3: Displaying the Market Dynamics- Drivers, Trends and Challenges & Opportunities of the Potato ChipsĬhapter 4: Presenting the Potato Chips Market Factor Analysis, Porters Five Forces, Supply/Value Chain, PESTEL analysis, Market Entropy, Patent/Trademark Analysis.Ĭhapter 5: Displaying the by Type, End User and Region/CountryĬhapter 6: Evaluating the leading manufacturers of the Potato Chips market which consists of its Competitive Landscape, Peer Group Analysis, BCG Matrix & Company ProfileĬhapter 7: To evaluate the market by segments, by countries and by Manufacturers/Company with revenue share and sales by key countries in these various regionsĬhapter 8 & 9: Displaying the Appendix, Methodology and Data Sourceįree Customization on the basis of client requirements on Immediate purchase:ġ- Free country-level breakdown of any 5 countries of your interest.Ģ- Competitive breakdown of segment revenue by market players. It can be better employed by both traditional and new players in the industry for complete know-how of the market. This section exclusively shares insight into the budget reports of big-league members of the market helping key players and new entrants understand the potential of investments in the Global Potato Chips Market. As the demand is driven by a buyer's paying capacity and the rate of item development, the report shows the important regions that will direct growth. The report covers the competitive analysis of the market. ![]() ![]() Speak To Our Analyst For A Discussion On The Above Findings, And Ask For A Discount On The Report Get in touch with our sales team, who will guarantee you a report that suits your needs. Customization of the reports as per your requirement is also offered. Prudent Markets provides attractive discounts that fit your needs. Supermarket/Hypermarket, Independent Retailer, Others Plain, Barbecue, Sour Cream & Onion, Salt & Vinegar, Others PepsiCo, Shearers, Pringles, Kettle Brand, Better Made, Cape Cod, Utz Quality Foods, Golden Flake, Mikesells, Ballreichsĭiscover Who You Really Compete Against In The Marketplace, Get PDF Sample Report Now! The report concludes with the profiles of major players in the Potato Chips market are: ![]() 5/16/2023 0 Comments Glass curio cabinet ikea![]() Another reason I chose the Fabrikor was that the Milsbo is frequently out of stock. Once I got my tape measure out and measured my space, I realized that the smaller version of the Fabrikor would have lots of room for plants. It’s worth noting that when comparing the cabinets, the smaller versions of the Fabrikor and the Milsbo seem pretty small, but I found that was only compared to the bigger versions. My decision to choose the smaller version of the Fabrikor was based on space and the design. Any of these would have worked for a greenhouse cabinet, in my opinion. I considered all of the different Ikea glass cabinets for my Ikea greenhouse hack. Ikea glass cabinet choices for greenhouse hacking Then I’ll talk a bit about adding lighting, monitoring the temperature and humidity, and more. So I’m going to walk you through the different Ikea glass cabinet choices, as well as which one I chose and why. (You’ll see my dry-air-loving snake plants on top-it’s perfect!) So I decided to prioritize my humidity-loving plants and put them in the cabinet. ![]() But as the air indoors got drier with the changing of the seasons, I realized I hated filling up the humidifier every day. Until this cabinet, I had most of my plants in this area on my DIY tiered plant stand. As a bonus, a closed cabinet also allows me to keep plants away from my kitties and daughter (though she loves to unlock the cabinet to “check” on the plants). So I decided to treat myself to this present when I realized that some of my humidity-loving plants would be better suited to a more moist environment. (Check out the Ikea Greenhouse Cabinet Instagram page for a ton of inspiration.) Today I’m sharing my birthday present to myself: an Ikea greenhouse cabinet hack using the beautiful Fabrikor! I have long admired Ikea greenhouse cabinets and all of the different ways people personalize them. Ikea greenhouse cabinet hack using the Fabrikor Check out how I decided on the Fabrikor and how I manage lighting, humidity, and organization. Looking for Ikea greenhouse cabinet ideas? I recently did an Ikea greenhouse hack using the Fabrikor cabinet, and it turned out fantastic. This is a very old cabinet and very heavy. Comes with brackets and glass shelves.96 inches long 40 inches high 20 inches deep.One end (glass) is broken but can be repaired. It is a glass enclosed display style cabinet. This is an old display cabinet used in my former business. ![]() wood and glass display cabinet (Pensacola).White bookshelf with doors/ display cabinet from IKEA (BILLY / OXBERG). IKEA Bookshelf/Display Cabinet - $100 (Laguna Niguel).Excellent Condition.Non-smoking home.But it's a smoking hot display cabinet. IKEA Nartorp Glass Display Cabinet with working light in RED!72" high x 17.5" wide x 15 3/4" deep. IKEA Nartorp Red Glass Display Cabinet - $175 (Old Town).Width: 16 3/4 inchesDepth: 14 3/8 inchesHeight: 64 1/8 inchesMax load/shelf: 8 lbHave colored RGB LED lights currently installed (different from whats shown in the first picture), will include for free. Ikea Detolf Glass display cabinet - $75 (West Bloomfield)įor sale:Ikea Detolf glass display cabinet with 3 glass shelves.Save yourself hours of frustrating assembly time complete with optional lighting fabulous for displaying whatever your collection may be 5 glass shelves and one metal one at the base approximately 71.5" x 15.75" x 17." shown standing on four furniture sliders. IKEA glass display cabinet - $300 (Helena). ![]() Measures:9.5 inches deep x 28.5 in high x 24 in wide $75Please email or text. 5/16/2023 0 Comments Spark chevrolet![]() ![]() The plant would instead produce the second-generation Trax. Production of the Spark at the Changwon, South Korea assembly plant ended in 2022. In the South Korean market, the Spark complies with South Korean "light car" ( Korean: 경차, romanized: Gyeongcha) regulations, which regulate overall vehicle dimensions and engine capacity with tax and parking fee benefits. The Spark EV was the first all-electric passenger car marketed by General Motors since the EV1 was discontinued in 1999, and the first ever offered for retail sale by GM (the EV1 was available only on lease). in selected markets in California and Oregon in June 2013. It also serves as the basis for the Opel Karl in Europe, Vauxhall Viva in the UK, and VinFast Fadil in Vietnam, the latter being manufactured under license.Ī limited-production all-electric version, the Chevrolet Spark EV, was released in the U.S. ![]() The fourth generation was launched in 2015, and also known as the Holden Spark in Australia and New Zealand. The third generation was predominantly marketed under its Chevrolet brand, including in North America as the Chevrolet Spark and in Australia and New Zealand as the Holden Spark Barina. In 2002, General Motors purchased Daewoo Motors, which had the vehicle being marketed with several GM marques and nameplates. The vehicle was initially developed by Daewoo and was introduced in 1998 as the Daewoo Matiz ( Korean: 대우 마티즈). The Chevrolet Spark ( Korean: 쉐보레 스파크) is a city car manufactured by General Motors's subsidiary GM Korea from 1998 to 2022. ![]() ![]() Combining waves can lead to constructive interference, in which peaks line up with peaks, or destructive interference, in which peaks line up with troughs ( Figure 8.28). Molecular orbitals are combinations of atomic orbital wave functions. The wave function describes the wavelike properties of an electron. The mathematical process of combining atomic orbitals to generate molecular orbitals is called the linear combination of atomic orbitals (LCAO). In these diatomic molecules, several types of molecular orbitals occur. Such molecules are called homonuclear diatomic molecules. We will consider the molecular orbitals in molecules composed of two identical atoms (H 2 or Cl 2, for example). Like an atomic orbital, a molecular orbital is full when it contains two electrons with opposite spin. The region of space in which a valence electron in a molecule is likely to be found is called a molecular orbital ( Ψ 2). Just like electrons around isolated atoms, electrons around atoms in molecules are limited to discrete (quantized) energies. Using quantum mechanics, the behavior of an electron in a molecule is still described by a wave function, Ψ, analogous to the behavior in an atom. Molecular orbital theory describes the distribution of electrons in molecules in much the same way that the distribution of electrons in atoms is described using atomic orbitals. Both theories provide different, useful ways of describing molecular structure. Table 8.2 summarizes the main points of the two complementary bonding theories. MO theory also helps us understand why some substances are electrical conductors, others are semiconductors, and still others are insulators. Unlike valence bond theory, which uses hybrid orbitals that are assigned to one specific atom, MO theory uses the combination of atomic orbitals to yield molecular orbitals that are delocalized over the entire molecule rather than being localized on its constituent atoms. Additionally, it provides a model for describing the energies of electrons in a molecule and the probable location of these electrons. It also explains the bonding in a number of other molecules, such as violations of the octet rule and more molecules with more complicated bonding (beyond the scope of this text) that are difficult to describe with Lewis structures. Molecular orbital theory (MO theory) provides an explanation of chemical bonding that accounts for the paramagnetism of the oxygen molecule. You can see videos of diamagnetic floating frogs, strawberries, and more. If you place a frog near a sufficiently large magnet, it will levitate. Living things contain a large percentage of water, so they demonstrate diamagnetic behavior. Water, like most molecules, contains all paired electrons. We can calculate the number of unpaired electrons based on the increase in weight. When we compare the weight of a sample to the weight measured in a magnetic field ( Figure 8.27), paramagnetic samples that are attracted to the magnet will appear heavier because of the force exerted by the magnetic field. Magnetic susceptibility measures the force experienced by a substance in a magnetic field. And yet, the Lewis structure of O 2 indicates that all electrons are paired. Such attraction to a magnetic field is called paramagnetism, and it arises in molecules that have unpaired electrons. ![]() Thus, when we pour liquid oxygen past a strong magnet, it collects between the poles of the magnet and defies gravity, as in Figure 8.1. ![]() By itself, O 2 is not magnetic, but it is attracted to magnetic fields. However, this picture is at odds with the magnetic behavior of oxygen. There is an O=O double bond, and each oxygen atom has eight electrons around it. This electronic structure adheres to all the rules governing Lewis theory. We would write the following Lewis structure for O 2: However, one of the most important molecules we know, the oxygen molecule O 2, presents a problem with respect to its Lewis structure. Relate these electron configurations to the molecules’ stabilities and magnetic propertiesįor almost every covalent molecule that exists, we can now draw the Lewis structure, predict the electron-pair geometry, predict the molecular geometry, and come close to predicting bond angles.Write molecular electron configurations for first- and second-row diatomic molecules.Calculate bond orders based on molecular electron configurations.Describe traits of bonding and antibonding molecular orbitals.Outline the basic quantum-mechanical approach to deriving molecular orbitals from atomic orbitals.Learning Objectives By the end of this section, you will be able to: ![]() |